Aluminium is known for its corrosion resistance. Untreated aluminium applications like traffic signs and applications at sea are respected examples. Although aluminium is a relatively non noble material it protects itself via a passive oxide layer. Corrosion resistance of Aluminium is sensitive upon certain points in particular, these will be addressed in this blog.
To design aluminium without corrosion take the following aspects into account.
- pH value of the environment
- Nobility of Aluminium
- Crevice corrosion
- Composition of Aluminum
- Black corrosion
pH value of the environment
Corrosion resistance of Aluminium is influenced strongly by the pH value of the environment
For normal use, like cleaning, use fluids in combinations with Aluminium with a pH neutral value (7) to prevent corrosion.
To prepare Aluminium for surface treatment you can use this to principle to clean the surface with specific sour fluids. The surface needs to be neutralized and rinsed adequately afterwards to prevent corrosion issues!
Nobility of Aluminium
To avoid corrosion problems with Aluminium nobility of the material needs to be taken into account. Aluminium is a relatively non noble material and will therefore sacrifice itself on behave of more noble metals in moister environment. This leads to galvanic corrosion.
This is a serious aspect using Aluminium products, specialy in combination with other metal parts. To prevent this type of corrosion block out fluids, use the right combinations of metals in the same nobility level or isolate the metals from each other.
In a moister environment fluid will creep between narrow crevice due to capillary motion. To prevent crevice corrosion you have to avoid small crevices. Crevice corrosion occurs between crevices with a distance in between 0.2 mm to 0.5 mm. The solution for this matter is to increase crevice distance and reduce amount of contact surfaces. For example: a line contact is better than a surface contact.
With acid or salt fluids the potential for crevice corrosion increases.
Composition of Aluminum
Last but not least, the composition of the aluminum alloy influences corrosion resistance of Aluminium. If corrosion resistance is low you can surface threat this material in different ways. Take into account it needs more effort than with better corrosion resistance material.
If you take these mechanisms into account your design is robust against most common corrosion issues. In that case you take advantage of the natural corrosion resistance of Aluminium.
What was your biggest insight about corrosion issues so fare?
Let me know in the comment box below. This way, you’re helping me and others to design a world with optimal Aluminium use… Thanks in advance!
Technological advancement will increase. We need materials that are available in abundance and can be recycled with no, or as little as possible, impact to the environment. Aluminium recycling is endless.
Product disposal, waste?
When the lifetime of a product ends there are two options: put it somewhere as waste and get environmental pollution or reuse the materials. For each material the possibilities for recycling are different. The big advantage of Aluminium is that you can reuse it time and time again without loss of quality/capability.. Due to the low required energy for recycling and it’s “easy” process, Aluminium is wanted for recycling.
The value of 1 kg Aluminium is equal to 1 kilo recycled Aluminium. (as long as the alloy is the same of course, more about that later). This means Aluminium waste = money. So Aluminium waste equals money.
Still some people’s perception is, I need primary material, although this is not relevant for Aluminium. The recipe of the alloy is key for the characteristics, primary or secondary.
Each Aluminium product has on average already 52% recycled metal content in Europe. Since Aluminium is a relatively young material, industrial production was only possible after 1886 asn opposed to e.g. the iron and it iron age around 1200 B.Chr.) we cannot supply the need at this moment with the current material available via recycling. (yet)
The value of Aluminium scrap depends on the composition. Aluminium can be selected on form which determines composition.
Aluminium alloys can be selected separated at the manufacturer, uniform scrap has the higher perceived value by the recycler.
After its product life time you can easily make an alloy selection by separating on form. E.g. if a building is stripped place the profiles on the profile bin, plates together at the plates and knots in the casting corner. You have now a very good separation of the different alloys quite easily.
There are lots of ways to separate alloys some are very basic like above some are very sophisticated. Since Aluminium = money, it’s worth it.
The value of Aluminium scrap also depends on the purity. For standard commercial alloys, the more pure, e.g. 99,5 % Al, the cheaper the Aluminium; if you apply it for its application. This is because these low strength alloy’s needed minimum work to fabricate. On the other hand, for recycling, this type of Aluminium with a low level of impurities can be used in many different Aluminium recipes, so value of the scrap is relatively high.
For household waste several possibilities are used. About 70% of all the Aluminium throw away is captured and reused. A welcome advantage here is Aluminium = money. So instead of costing money to burn or landfill it delivers income. For separation different processes can be used. E.g. like eddy current.
Because Aluminium is a conducted light material, it is influenced by the rotating magnet with North-south poles. This generates an eddy current. Aluminium pieces crossing this area get accelerated and separated.
So if your product consists of different materials you can either design for disassembly, then separate on form or shred into parts.
For Aluminium the loop today is nearly closed. From all the Aluminium material ever produced 75% is still in use. For automotive and building the recycling percentage is above 95%. Since manufacturers know exactly which alloy they prefer, manufacturers offer more and more to take their product back in return at the end of its lifetime. Although the recycling system in Europe is quite efficient and for environmental reasons this is not necessary, economically it can be beneficial. The closed loop of Aluminium will become shorter and more efficient. Just by the fact Aluminium is worth it.
Whats your biggest question about aluminium recycling? Please put your answer in the commentbox below. It will be appreciated! Thanks in advance.
Aluminium scandium alloys
With aluminium we can create all kind of forms. The material is ductile and form-able into all kinds of shapes. However an optimal design requires more effort to design. Start with your ideal form and then integrated functions.
What if we have something extra? Aluminium alloys which are 10 to 40% stronger? We will summarize the advantages on different areas when scandium is added in aluminium alloys .
First of all, strength of Aluminium alloys with scandium increases. This is shown if the graph above.
Next, recrystallization during coldwork (rolling) or extrusion is suppressed and prevented, which leads to better material quality.
Due to its fine grain refinement Scandium alloys reduces hot cracking in welds, increased strength in the welds and deliver better fatigue behavior. Welding filler/ thread with scandium has great potential for aluminium.
When will breakthrough appear?
Aluminium Scandium alloys are new and because of availability and price they aren’t popular jet. If they were used, it even happened that after product introduction the price of scandium was raised. On the other hand the amount of scandium used in aluminium was relatively high so price was effected drastically. Numbers of 10x material costs are mentioned.
This needs to be addressed before scandium will be commonly used in products.
Today, depending on the percentage of the scandium alloying element, the price of the aluminum with scandium will rice from 30% (at scandium levels of between 0.06 up to 0.12 wt% as used in Al-Zn-Mg (Cu) alloysand) up to e.g. 100%.
Price is under development. The process for mining and reduction is being optimized. Also a better quality scandium and lower quantities per alloy, generate a better proposition. For mining, new possibilities arise. This in total will be responsible for the acceptabele price levels. (make your comment if you want to know the source).
As mentioned in the past the scarcity leads to dramatic increase of price during application. And no one wants or can effort such surprises. Long term agreements are needed to solve this matter.
Benefits of scandium in aluminium alloys:
- Aluminium gets stronger
- Better weld-ability properties
- Grain structure during forming and extrusion stays intact
- Stronger at rising temperature, in combination with Zirconium.
Where do you want to use aluminium- scandium alloys in your products? Please write your comment below in the comment box and I sent you different sources for more information.
Would you like to stay informed about aluminium in English click here. Looking forward to your response!
Op verzoek van een van mijn klanten is dit BLOG in het Engels
On request of one of my customers this new BLOG is in English.
Aluminium is a corrosion resistant material and used frequently, even uncoated, in marine and offshore application with success. For various reasons surface treatment can be required, e.g. visual appearance or specific technical protection.
In all cases corrosion control starts at the construction table, with or without surface treatment.
Still, for coated products, corrosion can occur. Is it related to the use of aluminium or the way we use it?
In most cases problems can be avoided! As mentioned in the BLOG corrosion defects …
there are certain aluminium specific situations, to be aware of while using aluminium. For example, pH of the environment and nobility of the metals used in combination. If you would like to read that BLOG in English please make your request here and I will translate this for you.
This Blog focusses on the aspects to consider in order to prevent corrosion on coated aluminium.
Those are the aspects:
• Design for corrosion
• Material selection
• Coating system dedicated to the situation
The design, to prevent corrosion underneath a coating layer make sure the coating system is closed and has covered the entire part. Crevices, blank spots, or local tiny coating layers can be devastating, corrosion starts from these areas. Also chambers where water may remain will not be of any help for corrosion protection and should be prevented.
Aluminium itself is, depending on the alloy, A or B …, corrosion resistant. Alloy with copper or zinc for instance are more sensitive for corrosion as many of the aluminium magnesium alloys. Coaters have learned from experience that the corrosion index is also a good indicator for coat ability, but it is too complex just to use this “standard rule” as “the only truth” (or law). Knowledge at the coating partner and experience with the selected alloy are of great importance.
Pre-treatment is essential for coating on aluminium. If a company is not familiar with aluminium it will go wrong, with e.g. “delamination” of the coating layer as result. Aluminium can be coated in all kind of colors but doing so, takes quit some investments. A well applied pre-treatment plays a major role to paint adhesion and therefore is important for the overall protection.
Last but not least the coating system. What is the environment for your aluminium product? Is it in the middle of the dessert and should it be painted Ferrari red? Or is your application an aluminium coated trailer with marks on it and in severe dynamics circumstances? Every different situation needs another solution. If the basics are right the issues can be solved.
If all the issues are covered with the right knowledge or partners you will have lifetime well preserved aluminium products.
Please take good care of your aluminium product. Reminder; If possible clean regularly, with pH neutral cleanser! Together we can create a better world with the right use of aluminium!
Would you like to be informed about the possibilities with aluminium?
Subscribe to our mailing list.
Did you face difficulties with your coated aluminium products? Please leave your reaction below.